Good article on colour combinations. The focus here is on web design, but it can be easily applied to print as well. There are six different colour combinations described:
- Monochromatic
- Analogous
- Complementary
- Split Complementary
- Triadic
- Tetradic
1. Monochromatic

Using several tones of a single colour; such as light, medium and dark blue.
2. Analogous

Using three consecutive colours from the colour wheel; such as blue, green, lime
3. Complemenatry

Using two complementary colours, which are colours that are opposite each other on the colour wheel; such as violet and orange.
4. Split Complentary

Taking a colour, and the colours either side of the complementary colour; such as yellow with red and blue violet.
5. Triadic

Using three colours, equally spaced across the colour wheel; such as blue, lime and red.
6. Tetradic

Using four colours, equally spaced across the colour wheel; such as red, green, blue violet and orange.
Beginners Guide to Using the Power of Color in Web Design – Speckyboy Design Magazine.
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